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A New Route to Alkoxy Radicals — Photochemical Reactions with (Alkylperoxy)cobaloximes
Author(s) -
Hartung Jens,
Giese Bernd
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911240223
Subject(s) - chemistry , alkoxy group , radical , photochemistry , bond cleavage , catalysis , organic chemistry , alkyl
Abstract Alkoxy radicals have been generated by photochemical reactions of (alkylperoxy)cobaloximes 1 . The occurrence of alkoxy radicals has been proved by characteristic cyclization and β‐scission reactions of the reactive intermediates.