Dreikernige Niob‐Oxid‐Cluster 1) . – Synthese von (η 5 ‐C 5 Me 5 ) 3 Nb 3 (μ 2 ‐O) 3 (μ 3 ‐O)‐(μ 2 ‐Cl)Cl 3  und [(η 5 ‐C 5 Me 5 ) 3 Nb 3 (OH) 2 (μ 2 ‐OH)(μ 3 ‐OH)(μ 2 ‐O) 2 (μ 3 ‐O)Cl]Cl | Zendy

Leichtweis Iring | Zendy; Roesky Herbert W. | Zendy; Noltemeyer Mathias | Zendy; Schmidt HansGeorge | Zendy

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Dreikernige Niob‐Oxid‐Cluster 1) . – Synthese von (η 5 ‐C 5 Me 5 ) 3 Nb 3 (μ 2 ‐O) 3 (μ 3 ‐O)‐(μ 2 ‐Cl)Cl 3 und [(η 5 ‐C 5 Me 5 ) 3 Nb 3 (OH) 2 (μ 2 ‐OH)(μ 3 ‐OH)(μ 2 ‐O) 2 (μ 3 ‐O)Cl]Cl

Author(s) -

Leichtweis Iring,

Roesky Herbert W.,

Noltemeyer Mathias,

Schmidt HansGeorge

Publication year - 1991

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19911240202

Subject(s) - chemistry , yield (engineering) , crystallography , x ray crystallography , niobium , oxide , stereochemistry , materials science , organic chemistry , metallurgy , physics , diffraction , optics

Trinuclear Niobium Oxide Clusters 1) . – Synthesis of (η 5 ‐C 5 Me 5 ) 3 Nb 3 (μ 2 ‐O) 3 (μ 3 ‐O)(μ 2 ‐Cl)Cl 3 and [(η 5 ‐C 5 Me 5 ) 3 Nb 3 (OH) 2 (μ 2 ‐OH)(μ 3 ‐OH)(μ 2 ‐O) 2 (μ 3 ‐O)Cl]Cl Hydrolysis of η 5 ‐C 5 Me 5 NbCl 4 with excess of water leads to a mixture of products. Pyrolysis of this crude mixture gives (η 5 ‐C 5 Me 5 ) 3 Nb 3 (μ 2 ‐O) 3 (μ 3 ‐O)(μ‐Cl)Cl 3 ( 1 ) in good yield. On treatment of 1 with water [(η 5 ‐C 5 Me 5 ) 3 Nb 3 (OH) 2 (μ 2 ‐OH)(μ 3 ‐OH)(μ 2 ‐O) 2 (μ 3 ‐O)Cl]Cl ( 2 ) is obtained. The products 1 and 2 were characterized analytically and by X‐ray structure determination.

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