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Molecular Structure of Hg[C(COF)SF 2 O] 2
Author(s) -
Bittner Jürgen,
Seppelt Konrad
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911240114
Subject(s) - chemistry , intramolecular force , difluoride , xenon difluoride , fluorine , oxide , sulfur , molecule , crystallography , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry
Hg[C(COF) = SF 2 = O] 2 is prepared by the reaction of FCO CH = SF 2 = O with HgF 2 . This compound represents the third known example of an alkylidenesulfur difluoride oxide. Its molecular structure is the same as that of the most abundant of the three isomers of FCO‐CH = SF 2 = O. This is assumed to be the result of weak intramolecular Hg… O contacts. With the exception of the fluorine atoms bound to sulfur, all atoms lie approximately in one plane.