Notizen / Notes. Investigation on the Product from Monobutyltin(IV) Compounds and Benzoyl(thiobenzoyl)methane: a 1,3,2λ 5 ,4λ 5 ‐Dithiadistannetane | Zendy

Seth Neena | Zendy; Gupta Vishnu D. | Zendy; Linti Gerald | Zendy; Nöth Heinrich | Zendy

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Notizen / Notes. Investigation on the Product from Monobutyltin(IV) Compounds and Benzoyl(thiobenzoyl)methane: a 1,3,2λ 5 ,4λ 5 ‐Dithiadistannetane

Author(s) -

Seth Neena,

Gupta Vishnu D.,

Linti Gerald,

Nöth Heinrich

Publication year - 1991

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19911240113

Subject(s) - chemistry , tin , methane , dimer , yield (engineering) , medicinal chemistry , ring (chemistry) , sulfide , organic chemistry , metallurgy , materials science

Butyltin triisopropoxide reacts with benzoyl(thiobenzoyl)methane ( LH ) to yield BuSn(S)L and an organic sulfide 2 instead of the expected BuSnL 3 . The use of other butyltin(IV) starting materials invariably leads to the same products. From an X‐ray structure determination the tin sulfido complex is found to be a centrosymmetric dimer, [BuSn(S)L] 2 ( 1 ) with a planar four‐membered Sn 2 S 2 ring containing pentacoordinated tin atoms.

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