Darstellung eines viergliedrigen Indium‐Phosphor‐Rings mit am Phosphor gebundenem Wasserstoff. — Kristallstruktur von [(Me 3 SiCH 2 ) 2 InPH t Bu] 2 | Zendy

Dembowski Udo | Zendy; Noltemeyer Mathias | Zendy; Rockensüß Wilfried | Zendy; Stuke Michael | Zendy; Roesky Herbert W. | Zendy

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Darstellung eines viergliedrigen Indium‐Phosphor‐Rings mit am Phosphor gebundenem Wasserstoff. — Kristallstruktur von [(Me 3 SiCH 2 ) 2 InPH t Bu] 2

Author(s) -

Dembowski Udo,

Noltemeyer Mathias,

Rockensüß Wilfried,

Stuke Michael,

Roesky Herbert W.

Publication year - 1990

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19901231217

Subject(s) - chemistry , monoclinic crystal system , crystal structure , phosphor , indium , crystallography , ring (chemistry) , x ray crystallography , diffraction , physics , optoelectronics , organic chemistry , optics

Preparation of a Four‐Membered Indium‐Phosphorus Ring with a Hydrogen Atom Bound to Phosphorus. — Crystal Structure of [(Me 3 SiCH 2 ) 2 InPH t Bu] 2 Reaction of t BuPH 2 ( 1 ) with (Me 3 SiCH 2 ) 3 In ( 2 ) in the presence of Ag + ions leads to [(Me 3 SiCH 2 ) 2 InPH t Bu] 2 ( 3 ). According to an X‐ray structure analysis, 3 forms a four‐membered planar P 2 In 2 ring with alternating P — In bonds and crystallizes in the monoclinic space group C 2/ c .

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