Premium
Darstellung eines viergliedrigen Indium‐Phosphor‐Rings mit am Phosphor gebundenem Wasserstoff. — Kristallstruktur von [(Me 3 SiCH 2 ) 2 InPH t Bu] 2
Author(s) -
Dembowski Udo,
Noltemeyer Mathias,
Rockensüß Wilfried,
Stuke Michael,
Roesky Herbert W.
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901231217
Subject(s) - chemistry , monoclinic crystal system , crystal structure , phosphor , indium , crystallography , ring (chemistry) , x ray crystallography , diffraction , physics , optoelectronics , organic chemistry , optics
Preparation of a Four‐Membered Indium‐Phosphorus Ring with a Hydrogen Atom Bound to Phosphorus. — Crystal Structure of [(Me 3 SiCH 2 ) 2 InPH t Bu] 2 Reaction of t BuPH 2 ( 1 ) with (Me 3 SiCH 2 ) 3 In ( 2 ) in the presence of Ag + ions leads to [(Me 3 SiCH 2 ) 2 InPH t Bu] 2 ( 3 ). According to an X‐ray structure analysis, 3 forms a four‐membered planar P 2 In 2 ring with alternating P — In bonds and crystallizes in the monoclinic space group C 2/ c .