The laboratory generation of potentially interstellar cumulenes S(C n )S ( n  = 2–6) and their radical cations | Zendy

Sülzle Detlev | Zendy; Beye Norbert | Zendy; Fanghänel Egon | Zendy; Schwarz Helmut | Zendy

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The laboratory generation of potentially interstellar cumulenes S(C n )S ( n = 2–6) and their radical cations

Author(s) -

Sülzle Detlev,

Beye Norbert,

Fanghänel Egon,

Schwarz Helmut

Publication year - 1990

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19901231020

Subject(s) - chemistry , reionization , mass spectrometry , intermolecular force , tandem , gas phase , tandem mass spectrometry , phase (matter) , photochemistry , medicinal chemistry , molecule , organic chemistry , ion , ionization , materials science , chromatography , composite material

The title compounds are generated and characterized in the gas phase by tandem mass spectrometry (neutralization‐reionization mass spectrometry); it is demonstrated that both even and odd‐numbered polycarbon disulfides S(C n )S( n = 2–6) are stable species. The elusiveness of the even‐numbered analogues ( n = 2, 4, 6) in the condensed phase must be due to facile intermolecular reactions.

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