Alkinverbrückte Dreikerncluster mit Organo‐Rhodium‐Bausteinen | Zendy

Albiez Thomas | Zendy; Bantel Harald | Zendy; Vahrenkamp Heinrich | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Alkinverbrückte Dreikerncluster mit Organo‐Rhodium‐Bausteinen

Author(s) -

Albiez Thomas,

Bantel Harald,

Vahrenkamp Heinrich

Publication year - 1990

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19901230908

Subject(s) - rhodium , alkyne , chemistry , yield (engineering) , cluster (spacecraft) , metal , stereochemistry , polymer chemistry , medicinal chemistry , catalysis , organic chemistry , materials science , computer science , metallurgy , programming language

Alkyne‐Bridged Trinuclear Clusters with Organo‐Rhodium Moieties Several approaches are utilized to incorporate rhodium‐containing building blocks in alkyne‐bridged trinuclear clusters. The metal exchange procedure allows to introduce a Rh(CO) 3 unit into cluster 1 with formation of RuMoRhCp(CO) 8 (μ‐MeCCMe ( 6 ). Starting from dinuclear alkyne‐bridged complexes, RhCp units are attached, as in Co 2 RhCp(CO) 6 (μ‐HCCR) ( 10, 11 ) and CoMoRhCpCp*(CO) 5 (μ‐HCCR) ( 12 ). Side reactions yield tetranuclear clusters with Co 2 Rh 2 and Co 3 Rh frameworks.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research