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Multiple Bonds between Main Group Elements and Transition Metals, LXXXIII. Trioxo(pyrazolyl)rhenium(VII) and [Hydridotris(1‐pyrazolyl)borato‐ N,N′,N″ ]trioxorhenium(VII)
Author(s) -
Degnan Ian A.,
Herrman Wolfgang A.,
Herdtweck Eberhardt
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901230624
Subject(s) - chemistry , rhenium , monomer , transition metal , crystallography , stereochemistry , group (periodic table) , medicinal chemistry , organic chemistry , catalysis , polymer
The syntheses of the rhenium(VII) title compounds (pz)ReO 3 ( 1 ) and [HB(pz) 3 ]ReO 3 ( 2 ) (pz = pyrazolyl) are described. An X‐ray crystallographic study of 2 shows, that it has a monomeric structure.