Premium
Addukt eines fünfgliedrigen Trischwefeldistickstoffdioxid‐Rings an Titantetrachlorid
Author(s) -
Roesky Herbert W.,
Schimkowiak Jürgen,
Schmidt HansGeorg,
Noltemeyer Mathias,
Sheldrick George M.
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901230623
Subject(s) - chemistry , adduct , titanium tetrachloride , ring (chemistry) , recrystallization (geology) , crystallography , medicinal chemistry , tetrachloride , stereochemistry , titanium , organic chemistry , paleontology , tin , biology
Adduct of a Five‐Membered Trisulfurdinitrogen Dioxide Ring with Titanium Tetrachloride Reaction of S 6 N 4 O 4 with TiCl 4 lead to [(S 3 N 2 O 2 )TiCl 4 ] 2 ( 2 ). Single crystals of 2 were obtained by recrystallization from liquid SO 2 . 2 forms chains of five‐membered S 3 N 2 O 2 rings connected by Ti 2 Cl 8 units. The S 2 N 2 part of the five‐membered ring may be described as a 6‐π electron system.