Addukt eines fünfgliedrigen Trischwefeldistickstoffdioxid‐Rings an Titantetrachlorid | Zendy

Roesky Herbert W. | Zendy; Schimkowiak Jürgen | Zendy; Schmidt HansGeorg | Zendy; Noltemeyer Mathias | Zendy; Sheldrick George M. | Zendy

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Addukt eines fünfgliedrigen Trischwefeldistickstoffdioxid‐Rings an Titantetrachlorid

Author(s) -

Roesky Herbert W.,

Schimkowiak Jürgen,

Schmidt HansGeorg,

Noltemeyer Mathias,

Sheldrick George M.

Publication year - 1990

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19901230623

Subject(s) - chemistry , adduct , titanium tetrachloride , ring (chemistry) , recrystallization (geology) , crystallography , medicinal chemistry , tetrachloride , stereochemistry , titanium , organic chemistry , paleontology , tin , biology

Adduct of a Five‐Membered Trisulfurdinitrogen Dioxide Ring with Titanium Tetrachloride Reaction of S 6 N 4 O 4 with TiCl 4 lead to [(S 3 N 2 O 2 )TiCl 4 ] 2 ( 2 ). Single crystals of 2 were obtained by recrystallization from liquid SO 2 . 2 forms chains of five‐membered S 3 N 2 O 2 rings connected by Ti 2 Cl 8 units. The S 2 N 2 part of the five‐membered ring may be described as a 6‐π electron system.

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