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Synthese und Charakterisierung von (Iodcyan)iodonium‐hexafluoroarsenat, [ICNI] ⊕ [AsF 6 ] ⊖
Author(s) -
TornieporthOetting Inis,
Klapötke Thomas
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901230622
Subject(s) - chemistry , raman spectroscopy , cyanide , iodine , medicinal chemistry , crystallography , inorganic chemistry , organic chemistry , physics , optics
Synthesis and Characterization of (lodocyano)iodonium Hexafluoroarsenate. [ICNI] ⊕ [AsF 6 ] ⊖ (Iodocyano)iodonium hexafluoroarsenate, [ICNI] ⊕ [AsF 6 ] ⊖ ( 1 ), was synthesized quantitatively by the reaction of iodine cyanide with [I 3 ] ⊕ [AsF 6 ] ⊖ and was characterized by chemical analysis, IR, Raman and 19 F‐NMR data. The [ICNI] ⊕ cation in 1 represents the first example of its kind which is stable at room temperature, formally containing an N ⊕ ‐I bond.