β‐hydroxydithipozimtsäure als Ligand. Palladium(II)‐ und Platin(II)‐Komplexe von 2‐benzoyl‐1‐,1‐ethendithiolat. Kristallstrukturanalyse von  cis ‐{(Ph 3 P) 2 Pt[S 2 CCHC(O)C 6 H 5 ]} | Zendy

Weigand Wolfgang | Zendy; Bosl Gabriele | Zendy; Polborn Kurt | Zendy

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β‐hydroxydithipozimtsäure als Ligand. Palladium(II)‐ und Platin(II)‐Komplexe von 2‐benzoyl‐1‐,1‐ethendithiolat. Kristallstrukturanalyse von cis ‐{(Ph 3 P) 2 Pt[S 2 CCHC(O)C 6 H 5 ]}

Author(s) -

Weigand Wolfgang,

Bosl Gabriele,

Polborn Kurt

Publication year - 1990

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19901230621

Subject(s) - chemistry , palladium , platinum , ligand (biochemistry) , crystal structure , medicinal chemistry , stereochemistry , x ray crystallography , crystallography , catalysis , diffraction , organic chemistry , biochemistry , physics , receptor , optics

β‐Hydroxydithiocinnamic Acid as Ligand. Palladium(I1) and Platinum(I1) Complexes of 2‐Benzoyl‐1,l‐ethenedithiolate. Crystal Structure Analysis of cis ‐{(Ph 3 P) 2 Pt[S 2 CCHC(O)C 6 H 5 ]} β‐Hydroxydithiocinnamic acid reacts with L 2 Mcl 2 (L = Et 3 P, Ph 3 P, 1/2 dppe; M = Pd, Pt) to yield 2‐benzoyl‐1,1‐ethenedithiolate complexes L 2 M[S 2 CCHC(O)C 6 H 5 ] ( 2a : L = Ph 3 P, M = Pd; 2b : L = Et 3 P, M = Pt; 2c : L = Ph 3 P, m = Pt; 2d : L = 1/2 dppe, M = Pt). The compounds 2a – 2d were characterized by their spectroscopic data (IR; 1 H, 13 C, 31 P NMR); the structure of 2c was determined by X‐ray diffraction. A fluid solution of 2c shows fluorescence.

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