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9,10‐Phenanthrenocyaninatoeisen(II) (PhcFe) und axial koordinierte Isocyanid‐Komplexe
Author(s) -
Hanack Michael,
Renz Günter
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901230525
Subject(s) - chemistry , isocyanide , medicinal chemistry , stereochemistry
9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) and Axially Coordinated Isocyanide Complexes 9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) is synthesized from 9,10‐dicyanophenanthrene ( 3 ) and pentacarbonyliron. PhcFe exhibits similar spectroscopic properties (UV/VIS and Mößbauer spectra) and similar oxidation potentials as 1,2‐Naphthalocyaninatoiron(II) (1,2‐NcFe) and Phthalocyaninatoiron(II) (PcFe). Isocyanides RNC (R = t Bu, c Hx, Bzl, Me 2 Ph) react with PhcFe to form the corresponding bisaxially substituted 9,10‐phenanthrenocyaninatoiron(II) compounds 4–7 . Reaction of PhcFe with 1,4‐diisocyanobenzene (dib) yields the bridged complex [PhcFe(dib)] n .