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“Tuning” CH/CC Bond‐Activation Processes of Branched Amines by Choosing the Appropriate Gas‐Phase Transition‐Metal Ion
Author(s) -
Karaß Sigurd,
Eller Karsten,
Schwarz Helmut
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901230446
Subject(s) - chemistry , amine gas treating , gas phase , deuterium , metal , transition metal , ion , product distribution , inorganic chemistry , cyclic amines , medicinal chemistry , organic chemistry , catalysis , physics , quantum mechanics
The mechanisms of the deceptively similar gas‐phase chemistry of amine complexes RC(CH 3 ) 2 CH 2 NH 2 /M + (R = H, CH 3 M = Fe, Co, Ni) are uncovered by the use of deuterium‐labeled compounds. It is demonstrated that the details of CH/CC bond‐activation reactions are strongly metal‐ion‐dependent, as is the product distribution itself.