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syn/anti ‐Configurational Assignment of sec ‐Butalcarbinols Based on 13 C‐NMR Spectra
Author(s) -
Hildebrandt Bernhard,
Brinkmann Heinrich,
Hoffmann Reinhard W.
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901230436
Subject(s) - chemistry , diastereomer , nmr spectra database , spectral line , stereochemistry , carbon 13 nmr , carbon 13 nmr satellite , nuclear magnetic resonance spectroscopy , fluorine 19 nmr , physics , astronomy
syn or anti configuration 1 ) can be assigned to hte diastereomers of the sec ‐butylcarbinols 3 by analysis of diagnostic differences in the 13 C‐NMR spectra. Likewise, the 13 C‐NMR shifts of the diastereotopic methyl groups in isopropylacarbinols of type 19 have been assigned.