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Säurekatalysierte Umlagerung von Tetracyclo[6.3.0.0 4,11 .0 5,9 ]undec‐6‐en‐2‐on
Author(s) -
Ipaktschi Junes,
Herber Jürgen,
Kalinowski HansOtto,
Amme Monika,
Boese Roland
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901230214
Subject(s) - chemistry , formic acid , formate , enone , medicinal chemistry , stereochemistry , catalysis , organic chemistry
Acid‐Catalyzed Rearrangement of Tetracyclo[6.3.0.0 4,11 .0 5,9 ]undec‐6‐en‐2‐one The reaction of the enone 1 with formic acid selectively yields the formate 2 . The esters 3b and 4 are isolated as side products. The mechanism of this rearrangement is discussed.