Premium
An Uncomplexed 1,2,3‐Triborolane Derivative
Author(s) -
Meller Anton,
Bromm Dietmar,
Maringgele Walter,
Heine Andreas,
Stalke Dietmar,
Sheldrick George M.
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901230212
Subject(s) - chemistry , tris , borane , derivative (finance) , hexane , dicyclopentadiene , crystal structure , potassium , medicinal chemistry , stereochemistry , organic chemistry , catalysis , biochemistry , polymer , financial economics , economics , polymerization
(3α,4β,4aβ,7aβ,8β,8aα)‐1,2,3‐Tris(diisopropylamino)‐1,2,3,3a,44a,5,7a,8,8a‐decahydro‐4,8‐methanoindeno[5,6‐ d ]‐1,2,3‐triborol ( 1 ) is formed from dicyclopentadiene and dichloro(diisopropylamino)borane upon treatment with sodium/potassium alloy in hexane. 1,2,3‐Tris(diiso propylamino)triborane(5) ( 2 ) was also obtained. 1 is characterized by elemental analyses, spectroscopic data, and by an X‐ray structure analysis, 2 by its MS and NMR data.