An Uncomplexed 1,2,3‐Triborolane Derivative | Zendy

Meller Anton | Zendy; Bromm Dietmar | Zendy; Maringgele Walter | Zendy; Heine Andreas | Zendy; Stalke Dietmar | Zendy; Sheldrick George M. | Zendy

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An Uncomplexed 1,2,3‐Triborolane Derivative

Author(s) -

Meller Anton,

Bromm Dietmar,

Maringgele Walter,

Heine Andreas,

Stalke Dietmar,

Sheldrick George M.

Publication year - 1990

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19901230212

Subject(s) - chemistry , tris , borane , derivative (finance) , hexane , dicyclopentadiene , crystal structure , potassium , medicinal chemistry , stereochemistry , organic chemistry , catalysis , biochemistry , polymer , financial economics , economics , polymerization

(3α,4β,4aβ,7aβ,8β,8aα)‐1,2,3‐Tris(diisopropylamino)‐1,2,3,3a,44a,5,7a,8,8a‐decahydro‐4,8‐methanoindeno[5,6‐ d ]‐1,2,3‐triborol ( 1 ) is formed from dicyclopentadiene and dichloro(diisopropylamino)borane upon treatment with sodium/potassium alloy in hexane. 1,2,3‐Tris(diiso propylamino)triborane(5) ( 2 ) was also obtained. 1 is characterized by elemental analyses, spectroscopic data, and by an X‐ray structure analysis, 2 by its MS and NMR data.

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