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Gold(I) Complexes of Primary Phosphanes: Pair Formation through Au…Au Interactions
Author(s) -
Schmidbaur Hubert,
Weidenhiller Gabriele,
Steigelmann Oliver,
Müller Gerhard
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901230210
Subject(s) - chemistry , alkyl , primary (astronomy) , molecule , crystal structure , stereochemistry , crystallography , medicinal chemistry , organic chemistry , physics , astronomy
(CO)AuCl reacts with (2,4,6‐trialkylphenyl)phosphanes 1a – d (alkyl = Me, Et, i Pr, t Bu) to give the 1:1 complexes 2a – d . The crystal structure of 2d shows pairs of molecules with Au…Au contacts of 3.440(1) Å.