Regiospecific Activation of C–H Bonds in Fe +  Complexes of ω‐Silyl‐substituted Alkanenitriles Caused by Metal‐Ion‐Mediated Cooperative Effects of Functional Groups | Zendy

Hässelbarth Alexander | Zendy; Prüsse Tilmann | Zendy; Schwarz Helmut | Zendy

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Regiospecific Activation of C–H Bonds in Fe + Complexes of ω‐Silyl‐substituted Alkanenitriles Caused by Metal‐Ion‐Mediated Cooperative Effects of Functional Groups

Author(s) -

Hässelbarth Alexander,

Prüsse Tilmann,

Schwarz Helmut

Publication year - 1990

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19901230134

Subject(s) - chemistry , reactivity (psychology) , silylation , molecule , metal , medicinal chemistry , stereochemistry , ion , crystallography , catalysis , organic chemistry , medicine , alternative medicine , pathology

In contrast to the monofunctinal compounds (i.e. 8,8‐dimethylnonanenitrile and n ‐heptyltrimethylsilane) the Fe + complex of 7‐trimethylsilyheptanenitrile (2‐Fe + ) exhibits a unique reactivity in the gas phase which can only be explained by invoking a metal‐ion‐mediated cooperation of the SiMe 3 and the CN group resulting in the regiospecific activation of C–H bonds. In contrast tot he Fe + complexes of the monofunctional molecules, no C–C bond activation is observed for 2–Fe + .

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