Mononuclear Bis(diazadiene)ruthenium(0) Complexes and the Coupling of Butadiene to a Diazadiene System | Zendy

Rosenberger Volker | Zendy; Dieck Heindirk Tom | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Mononuclear Bis(diazadiene)ruthenium(0) Complexes and the Coupling of Butadiene to a Diazadiene System

Author(s) -

Rosenberger Volker,

Dieck Heindirk Tom

Publication year - 1990

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19901230117

Subject(s) - chemistry , 1,3 butadiene , ruthenium , hydride , ethylene , medicinal chemistry , coupling (piping) , magnesium , stereochemistry , photochemistry , metal , catalysis , organic chemistry , metallurgy , materials science

Complexes (dad) 2 RuCl 2 ( 1 ) (dad = diazadiene, RN = CR'– CR'=NR) are reduced to (dad) 2 Ru ( 2 ) which react with L = CO or ethylene to give (dad) 2 RuL ( 3,5 ). Reduction of 1b ( R' = H) with magnesium–butadiene or reaction of 2b with butadiene leads to a new type of C–C coupling of butadiene to one of the diazadiene ligands ( 6b ). Addition of CO induces a rearrangement to 7b by a hydride shift.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research