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Cyclische Natrium‐ und Kalium‐(fluorsilyl)phosphide – Synthesen und Kristallstrukturen
Author(s) -
Andrianarison Mbolatiana,
Stalke Dietmar,
Klingebiel Uwe
Publication year - 1990
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19901230114
Subject(s) - chemistry , phosphide , potassium , sodium , phosphine , crystal structure , alkali metal , medicinal chemistry , stereochemistry , crystallography , organic chemistry , metal , catalysis
Cyclic Sodium and Potassium (Fluorosily1)phosphides ‐ Syntheses and Crystal Structures (Di‐ tert ‐butylfluorosilyl)(mesityl)phosphine ( 1 ) reacts with sodium or potassium to give the alkali compounds [(CMe 3 ) 2 SiFM(THF) 2 PC 6 H 2 Me 3 ] 2 ( 2 : M = Na; 3 : M = K). The crystal structures of the eight‐membered rings 2 and 3 have been determined.