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Hetero‐π‐Systeme, 17: Aminosilylen (Aminosilandiyl)
Author(s) -
Maier Günther,
Glatthaar Jörg,
Reisenauer Hans Peter
Publication year - 1989
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19891221231
Subject(s) - chemistry , photodissociation , silylation , argon , irradiation , azide , photochemistry , matrix isolation , hydrogen , organic chemistry , catalysis , physics , nuclear physics
Hetero π‐Systems, 17. — Aminosilylen (Aminosilanediyl) Aminosilylene can be prepared by 254‐nm photolysis of silyl azide isolated in an argon matrix at 12 K. Subsequent irradiation with wavelengths > 300 nm yields silaisonitrile ( 3 ) and molecular hydrogen. This reaction may be reversed with 254‐nm light.