Nitroxide (Aminyloxide), XLII: Die Isolierung des ersten OC‐verknüpften Dimeren eines Vinylnitroxids | Zendy

Aurich Hans Günter | Zendy; Keßler Wilfried | Zendy

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Nitroxide (Aminyloxide), XLII: Die Isolierung des ersten OC‐verknüpften Dimeren eines Vinylnitroxids

Author(s) -

Aurich Hans Günter,

Keßler Wilfried

Publication year - 1989

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19891221228

Subject(s) - chemistry , nitroxide mediated radical polymerization , nitrone , dimer , aldehyde , tetra , polymer chemistry , stereochemistry , organic chemistry , medicinal chemistry , monomer , catalysis , polymer , cycloaddition , radical polymerization

Nitroxides (Aminyl Oxides), XLII. — The Isolation of the First OC‐Bonded Dimer of a Vinyl Nitroxide Vinyl nitroxide 2 , formed by oxidation of nitrone 1 , with lead dioxide, affords the OC dimer 3 . Oxidation of 1 proceeds rather slowly. A high oxidation potential is found for 1 . However, if vinyl nitroxide 2 is generated from the vinylhydroxylamine 4 , the aldehyde 7 is formed by a complex reaction sequence.

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