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Ein makrobicyclischer Großhohlraum zur selektiven Komplexierung von Alkalimetall‐Ionen
Author(s) -
PeterKatalinić Jasna,
Ebmeyer Frank,
Seel Christian,
Vögtle Fritz
Publication year - 1989
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19891221227
Subject(s) - chemistry , alkali metal , ligand (biochemistry) , selectivity , polymer chemistry , inorganic chemistry , medicinal chemistry , organic chemistry , catalysis , biochemistry , receptor
A Large Macrobicyclic cavity for the Selective Complexation of Alkali Metal Ions The preparation of the new ligand 3 was carried out starting with the podand 8 and the triamine 11 . Ligand 3 forms complexes with alkali metal ions in solution (chloroform) as well as under the conditions of FAB mass spectrometry, whereby Cs ⊕ selectivity is observed.