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Synthese und Eigenschaften von iPr 2 InCl, iPrInCl 2 und (iPr 2 InNHtBu) 2
Author(s) -
Neumüller Bernhard
Publication year - 1989
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19891221214
Subject(s) - chemistry , solid state , medicinal chemistry , chloride , stereochemistry , organic chemistry
Synthesis and Properties of iPr 2 InCl, iPrInCl 2 , and (iPr 2 InHRtBu) 2 The reactions of triisopropylindium ( 1 ) with half an equivalent or two equivalents of indium (III) chloride leads to iPr 2 InCl ( 2 ) and iPrInCl 2 ( 3 ), respectively. (iPr 2 InNHtBu) 2 ( 4 ) can be synthesized from 2 and LiNHtBu. According to NMR, IR, and RE studies, 2 – 4 from dimers in solution and solid state. The X‐ray analysis of 4 is reported.