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Darstellung und Struktur eines neungliedrigen Niob‐haltigen Heterocyclus mit oxidischen und nitridischen Struktureinheiten
Author(s) -
Roesky Herbert W.,
Liebermann Johannes,
Noltemeyer Mathias,
Schmidt HansGeorg
Publication year - 1989
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19891220907
Subject(s) - chemistry , niobium , crystal structure , stereochemistry , medicinal chemistry , crystallography , organic chemistry
Synthesis and X‐ray Structure of a Nine‐Membered Heterocycle Containing Niobium and Oxidic and Nitridic Structural Elements (Me 3 SiNPPh 2 CH 2 ) 2 ( 1 ) reacts with NbCl 5 to form (H 2 CPPh 2 NNbCl 4 ) 2 ( 2 ). The reaction of 2 with THF yields the nine‐membered metallaheterocycle ( 3 ). Simultaneously, (ClCH 2 CH 2 ) 2 is produced. The X‐ray structure of 3 is reported.
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