Premium
Methylthiovinyl als Komplexligand — Deprotonierung von Dicarbonyl‐(η 5 ‐cyclopentadienyl)[η 2 ‐methyl(methylthio)carben]wolfram‐tetrafluoroborat
Author(s) -
Kreißl Fritz R.,
Ullrich Norbert
Publication year - 1989
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19891220819
Subject(s) - carbene , chemistry , tetrafluoroborate , cyclopentadienyl complex , triethylamine , deprotonation , tungsten , medicinal chemistry , ligand (biochemistry) , organic chemistry , ion , catalysis , ionic liquid , biochemistry , receptor
Methylthiovinyl as a New Ligand ‐ Deprotonation of Dicarbonyl(η 5 ‐cyclopentadienyl)[η 2 ‐methyl(methylthio)carbene]tungsten Tetrafluoroborate Triethylamine deprotonates the C ‐methyl group in dicarbonyl‐(η 5 ‐cyclopentadienyl)[η 2 ‐methylthio)carbene]tungsten tetrafluoroborate to provide the neutral methylthiovinyl complex of tungsten.