Methylthiovinyl als Komplexligand — Deprotonierung von Dicarbonyl‐(η 5 ‐cyclopentadienyl)[η 2 ‐methyl(methylthio)carben]wolfram‐tetrafluoroborat | Zendy

Kreißl Fritz R. | Zendy; Ullrich Norbert | Zendy

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Methylthiovinyl als Komplexligand — Deprotonierung von Dicarbonyl‐(η 5 ‐cyclopentadienyl)[η 2 ‐methyl(methylthio)carben]wolfram‐tetrafluoroborat

Author(s) -

Kreißl Fritz R.,

Ullrich Norbert

Publication year - 1989

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19891220819

Subject(s) - carbene , chemistry , tetrafluoroborate , cyclopentadienyl complex , triethylamine , deprotonation , tungsten , medicinal chemistry , ligand (biochemistry) , organic chemistry , ion , catalysis , ionic liquid , biochemistry , receptor

Methylthiovinyl as a New Ligand ‐ Deprotonation of Dicarbonyl(η 5 ‐cyclopentadienyl)[η 2 ‐methyl(methylthio)carbene]tungsten Tetrafluoroborate Triethylamine deprotonates the C ‐methyl group in dicarbonyl‐(η 5 ‐cyclopentadienyl)[η 2 ‐methylthio)carbene]tungsten tetrafluoroborate to provide the neutral methylthiovinyl complex of tungsten.

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