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Beiträge zur Koordinationschemie des tert ‐Butyldifluorphosphans, 1: Hexakis( tert ‐butyldifluorphosphan)wolfram(0) — Synthese, Eigenschaften, Spektren und Kristallstruktur
Author(s) -
Krampe Willi,
Kruck Thomas,
Tebbe KarlFriedrich
Publication year - 1989
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19891220816
Subject(s) - chemistry , crystal structure , tungsten , crystallography , nmr spectra database , coordination complex , x ray crystallography , stereochemistry , spectral line , diffraction , metal , organic chemistry , physics , optics , astronomy
Contributions to the Coordination Chemistry of tert ‐Butyldifluorophosphine, 1. ‐ Hexakis( tert ‐butyldifluorophosphine)tungsten(0) ‐ Synthesis, Chemical Properties, Spectra, and Crystal Structure Synthesis, chemical properties, NMR and IR spectra of hexakis( tert ‐butyldifluorophosphane)tungsten(0) ( 4 ) are described. Its crystal structure was determined by X‐ray diffraction. 4 is the first coordination compound with more than four bulky P t BuF 2 ligands.

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