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Complexes with sterically demanding ligands, VI: Synthesis and reactivity of mono[tris(trimethylsilyl)cyclopentadienyl]iron(trimethyl phosphite) complexes
Author(s) -
Okuda Jun
Publication year - 1989
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19891220709
Subject(s) - chemistry , trimethylsilyl , tris , reactivity (psychology) , cyclopentadienyl complex , steric effects , medicinal chemistry , trimethyl phosphite , stereochemistry , organic chemistry , catalysis , medicine , biochemistry , alternative medicine , pathology
A direct synthesis of iron(trimethyl phosphite) half‐sandwich complexes [η 5 ‐C 5 H 2 (SiMe 3 ) 3 ]Fe[P(OMe) 3 ] 2 X starting from FeX 2 (X = Cl, Br, I) and Li[η 5 ‐C 5 H 2 (SiMe 3 ) 3 ] is described. Their reactivity toward t BuMgCl and CO has been studied.