Tris(trimethylsilyl)methantellurenylhalogenide (Me 3 Si) 3 CTeX (X = Cl, Br, I): Synthese stabiler Alkantellurenylhalogenide | Zendy

Giselbrecht Karlheinz | Zendy; Bildstein Benno | Zendy; Sladky Fritz | Zendy

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Tris(trimethylsilyl)methantellurenylhalogenide (Me 3 Si) 3 CTeX (X = Cl, Br, I): Synthese stabiler Alkantellurenylhalogenide

Author(s) -

Giselbrecht Karlheinz,

Bildstein Benno,

Sladky Fritz

Publication year - 1989

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19891220707

Subject(s) - trimethylsilyl , chemistry , tris , halide , bromide , iodide , medicinal chemistry , methyl iodide , organic chemistry , biochemistry

Tris (trimethylsilyl)methanetellurenyl Halides (Me 3 Si) 3 CTex (X = Cl, Br, I): Synthesis of Stable Alkanetellurenyl Halides The first stable and isolable alkanetellurenyl halides, tris(trimethylsilyl)methanetellurenyl chloride, bromide, and iodide ( 1a – c ) are obtained quantitatively by halogenolysis of bis[tris‐(trimethylsilyl)methyl] ditelluride with SO 2 Cl 2 , Br 2 , and I 2 , respectively. Their synthetic potential is examplified by transformation to methyl tris(trimethylsilyl)methyl telluride ( 2 ) and phenyl tris(trimethylsilyl)methyl telluride ( 3 ).

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