Notizen / Notes Metallorganische Lewis‐Säuren, XXXIX. σ,π‐Ethinid‐verbrückte Rhenium‐Eisencarbonyle [(OC) 5 Re (μ‐η 1 :η 2 ‐CCR)‐Fe(CO) 2 Cp] + BF 4  −  (R = Me, Ph) | Zendy

Fritz Peter M. | Zendy; Polborn Kurt | Zendy; Steimann Manfred | Zendy; Beck Wolfgang | Zendy

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Notizen / Notes Metallorganische Lewis‐Säuren, XXXIX. σ,π‐Ethinid‐verbrückte Rhenium‐Eisencarbonyle [(OC) 5 Re (μ‐η 1 :η 2 ‐CCR)‐Fe(CO) 2 Cp] + BF 4 − (R = Me, Ph)

Author(s) -

Fritz Peter M.,

Polborn Kurt,

Steimann Manfred,

Beck Wolfgang

Publication year - 1989

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19891220516

Subject(s) - rhenium , chemistry , lewis acids and bases , group 2 organometallic chemistry , electrophile , medicinal chemistry , stereochemistry , molecule , crystallography , catalysis , inorganic chemistry , organic chemistry

Organometallic Lewis Acids, XXXIX. – σ, π‐Ethynide Bridged Rhenium Iron Carbonyls [(OC) 5 Re(μ‐η 1 :η 2 ‐C)‐Fe(CO) 2 Cp] + BF 4 − (R = Me, Ph) The addition of Re(CO) 5 + [as Re(CO) 5 FBF 3 ] to Cp(OC) 2 ‐FeCCR (R = Me, Ph) gives under electrophilic substitution of Fe(CO) 2 Cp + by Re(CO) 5 + the σ,π‐ethynide bridged title complexes 1 of which the phenylethynide compound 1a has been characterized by X‐ray structural analysis.

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