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Infrared Spectra and Photochemistry of Isodiazene and Its Deuterated Isotopomers
Author(s) -
Teles Joaquim Henrique,
Maier Günther,
Andes Hess B.,
Schaad Lawrence J.
Publication year - 1989
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19891220424
Subject(s) - isotopomers , chemistry , matrix isolation , infrared , deuterium , infrared spectroscopy , ab initio quantum chemistry methods , photochemistry , ab initio , spectral line , computational chemistry , kinetic isotope effect , molecule , organic chemistry , atomic physics , physics , optics , astronomy
The matrix isolation of aminoisocyanate opens a new efficient route for the preparation of isodiazene (aminonitrene). Its infrared spectrum can now, with the help of ab initio calculations, be interpreted, and its photochemistry can be studied.