Synthesis and Properties of a (Phthalocyaninato)copper(II) Complex Symmetrically Substituted with Eight Crown Ethers | Zendy

Sarigül Sevgi | Zendy; Bekâroǧlu Özer | Zendy

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Synthesis and Properties of a (Phthalocyaninato)copper(II) Complex Symmetrically Substituted with Eight Crown Ethers

Author(s) -

Sarigül Sevgi,

Bekâroǧlu Özer

Publication year - 1989

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19891220214

Subject(s) - chemistry , crown ether , quinoline , copper , intramolecular force , pyridine , crown (dentistry) , metal , medicinal chemistry , alkali metal , polymer chemistry , ether , ion , inorganic chemistry , stereochemistry , organic chemistry , medicine , dentistry

A soluble (phthalocyaninato)copper(II) complex containing eight symmetrical benzo‐15‐crown‐5 substituents, namely {2,3,9,10,16,17,23,24‐octakis[[benzo‐15‐crown‐5)‐4′ ‐yl]oxymethyl]phthalocyaninato}copper(II) ( 2 ) from 1,2‐bis{[benzo‐15‐crown‐5)‐4′‐yl]oxymethyl}‐4,5‐dibromobenzene ( 1 ) and CuCN in quinoline or pyridine was synthesized. The crown‐ether groups in 2 were shown to prefer intramolecular complexation with alkali metal ions.

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