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Notizen Oxidative Addition mit 5‐Brompentamethyl‐1,3‐cyclopentadien: Ein neues Verfahren zur Synthese von (Pentamethylcyclopentadienyl)‐metall‐Verbindungen
Author(s) -
Jutzi Peter,
Schwartzen KarlHeinz
Publication year - 1989
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19891220212
Subject(s) - chemistry , oxidative addition , stannane , medicinal chemistry , cyclopentadiene , tin , antimony , organic chemistry , catalysis
Oxidative Addition with 5‐Brompentamethyl‐1,3‐cyclopentadiene: A new Method for the Synthesis of (Pentamethylcyclopentadienyl)metall Compounds The metals antimony, bismuth, tin, and magnesium react with Me 5 C 5 Br ( 1 ) in good yields and under mild conditions to give pentamethylcyclopentadienyl compounds of the type (Me 5 C 5 ) x MBr y ( 2 , 3 , 6 , 8 ). The reaction of decamethylstannocene (7) or bromo(pentamethylcyclopentadienyl)stannylene ( 5 ) with 1 leads to dibromobis(pentamethylcyclopentadienyl)stannane ( 6 ).