Notizen Oxidative Addition mit 5‐Brompentamethyl‐1,3‐cyclopentadien: Ein neues Verfahren zur Synthese von (Pentamethylcyclopentadienyl)‐metall‐Verbindungen | Zendy

Jutzi Peter | Zendy; Schwartzen KarlHeinz | Zendy

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Notizen Oxidative Addition mit 5‐Brompentamethyl‐1,3‐cyclopentadien: Ein neues Verfahren zur Synthese von (Pentamethylcyclopentadienyl)‐metall‐Verbindungen

Author(s) -

Jutzi Peter,

Schwartzen KarlHeinz

Publication year - 1989

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19891220212

Subject(s) - chemistry , oxidative addition , stannane , medicinal chemistry , cyclopentadiene , tin , antimony , organic chemistry , catalysis

Oxidative Addition with 5‐Brompentamethyl‐1,3‐cyclopentadiene: A new Method for the Synthesis of (Pentamethylcyclopentadienyl)metall Compounds The metals antimony, bismuth, tin, and magnesium react with Me 5 C 5 Br ( 1 ) in good yields and under mild conditions to give pentamethylcyclopentadienyl compounds of the type (Me 5 C 5 ) x MBr y ( 2 , 3 , 6 , 8 ). The reaction of decamethylstannocene (7) or bromo(pentamethylcyclopentadienyl)stannylene ( 5 ) with 1 leads to dibromobis(pentamethylcyclopentadienyl)stannane ( 6 ).

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