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Über die Umlagerung eines tricyclischen, ungesättigten Ketons bei der Wolff‐Kishner‐Reduktion
Author(s) -
Otterbach Andreas,
Musso Hans
Publication year - 1988
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19881211228
Subject(s) - chemistry , ketone , medicinal chemistry , stereochemistry , organic chemistry
On the Rearrangement of a Tricyclic Unsaturated Ketone during Wolff‐Kishner Reduction Wolff‐Kishner reduction of tricyclo[4.2.1.1 2,5 ]dec‐3‐en‐9‐one ( 1 ) yields only 2–9% of the expected olefin 7 , 1–3% of the syn isomer 8 , but 17–26% of bi(1‐cyclopentenyl) ( 5 ).
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