Thermolysis of oxazolin‐5‐ones, 12. Formation of a cage compound by thermolysis of 2‐(4‐Chlorophenyl)‐2‐(3,3‐dimethylallyl)‐4‐phenyl‐5(2 H )‐oxazolone | Zendy

Fischer János | Zendy; Márványos Ede | Zendy; Párkányi László | Zendy; Kálmán Alajos | Zendy; Steglich Wolfgang | Zendy

Premium

Thermolysis of oxazolin‐5‐ones, 12. Formation of a cage compound by thermolysis of 2‐(4‐Chlorophenyl)‐2‐(3,3‐dimethylallyl)‐4‐phenyl‐5(2 H )‐oxazolone

Author(s) -

Fischer János,

Márványos Ede,

Párkányi László,

Kálmán Alajos,

Steglich Wolfgang

Publication year - 1988

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19881210926

Subject(s) - chemistry , thermal decomposition , cage , oxazolone , stereochemistry , medicinal chemistry , decomposition , organic chemistry , combinatorics , mathematics

During thermolysis of title compound 1 , the unusual cage compound 4 is formed (along with 2,3‐dihydropyridine 3 ); the structure of 4 was determined by X‐ray structure analysis. The formation of 4 can be explained by dimerization of the intermediates 2 and 3 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research