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Thermolysis of oxazolin‐5‐ones, 12. Formation of a cage compound by thermolysis of 2‐(4‐Chlorophenyl)‐2‐(3,3‐dimethylallyl)‐4‐phenyl‐5(2 H )‐oxazolone
Author(s) -
Fischer János,
Márványos Ede,
Párkányi László,
Kálmán Alajos,
Steglich Wolfgang
Publication year - 1988
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19881210926
Subject(s) - chemistry , thermal decomposition , cage , oxazolone , stereochemistry , medicinal chemistry , decomposition , organic chemistry , combinatorics , mathematics
During thermolysis of title compound 1 , the unusual cage compound 4 is formed (along with 2,3‐dihydropyridine 3 ); the structure of 4 was determined by X‐ray structure analysis. The formation of 4 can be explained by dimerization of the intermediates 2 and 3 .