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Neue Bicyclen mit P(V)–P(III)–P(V)‐Bindungen
Author(s) -
Roesky Herbert W.,
Scholz Uwe,
Schmidpeter Alfred,
Karaghiosoff Konstantin,
Sheldrick William S.
Publication year - 1988
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19881210922
Subject(s) - chemistry , bicyclic molecule , molar ratio , medicinal chemistry , stereochemistry , organic chemistry , catalysis
A New Bicyclic System with a P(V)–P (III)–P(V) Unit PhCN 2 (SiMe 3 ) 3 ( 1 ) reacts with PhPCl 2 in a molar ratio of 2:3 to give the bicyclic system 2 with a P(V)–P(III)–P(V) unit, characterized by an X‐ray structure analysis. Dichlorophenylphosphane reacts with [Me 2 NC(NH 2 ) 2 ]Cl ( 3 ) to form 4 . The reaction of Me 2 NCN with LiN(SiMe 3 ) 2 and PhPCl 2 yields 5 containing a P(V)–P(III)–P(III)–P(V) chain.
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