Synthese von Bis(cyclopentadienyl)‐1‐metalla‐3‐phosphaindenen (M  Titan, Zirkonium) | Zendy

Binger Paul | Zendy; Biedenbach Bruno | Zendy; Mynott Richard | Zendy; Regitz Manfred | Zendy

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Synthese von Bis(cyclopentadienyl)‐1‐metalla‐3‐phosphaindenen (M  Titan, Zirkonium)

Author(s) -

Binger Paul,

Biedenbach Bruno,

Mynott Richard,

Regitz Manfred

Publication year - 1988

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19881210818

Subject(s) - chemistry , cyclopentadienyl complex , zirconium , titanium , reagent , medicinal chemistry , crystal structure , metallocene , organic chemistry , catalysis , polymerization , polymer

Synthesis of Bis(cyclopentadienyl)‐1‐metalla‐3‐phosphaindenes (M= Titanium, Zirconium) The title compounds 7a, b were synthesised by heating the bis(cyclopentadienyl)diphenylmetal complexes 4a, b to 80°C in the presence of an excess of 2‐ tert ‐butyl‐1‐phosphaacetylene ( 6 ). The structure of 7a, b was determined by spectroscopic methods.

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