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Complexes with carbon sulfides and selenides as ligands, XXIII. Synthesis of Pt(CS)(PPh 3 ) 2 ) and Pt(CE)(dpmb) (E = S, Se): The First Mononuclear Thio‐ and Selenocarbonyl Complexes of Platinum(0)
Author(s) -
Ebner Martin,
Werner Helmut
Publication year - 1988
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19881210816
Subject(s) - chemistry , platinum , thio , medicinal chemistry , stereochemistry , catalysis , organic chemistry
(PPh 3 ) 2 Pt(μ‐CS 2 )Pt(PPh 3 ) 2 ( 1 ) and (dpmb)Pt(μ‐CE 2 )Pt(PPh 3 ) 2 ( 2 : E S; 3 : E Se) on heating at 40–70°C give the complexes Pt(CS)(PPh 3 ) 2 ( 4 ) and Pt(CE)(dpmb)( 5 : E S; 6 E Se), which are the first mononuclear thio‐ and selenocarbonyl complexes of platinum(0).
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