Premium
Beiträge zur Chemie des Bors, 192. Reaktionen von Quecksilberdihalogeniden und Quecksilberdicyanid mit einem Aminoiminoboran
Author(s) -
Brandl Andreas,
Nöth Heinrich
Publication year - 1988
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19881210727
Subject(s) - chemistry , allene , mercury (programming language) , adduct , nuclear magnetic resonance spectroscopy , medicinal chemistry , stereochemistry , organic chemistry , catalysis , computer science , programming language
Contributions of the Chemistry of Boron, 192. ‐ Reactions of Mercury Dihalides and Mercury Dicyanide with an Aminoiminoborane The aminoiminoborane 1 reacts with HgCl 2 and Hg(CN) 2 with insertion into the HgCl and HgC bond, respectively. Mercury amides of type 2 are obtained. In contrast, HgBr 2 and HgI 2 yield 1:1 adducts of the allene type 3 . The new compounds were characterized by IR and NMR spectroscopy.