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Pentaphosphametallocene
Author(s) -
Scherer Otto. J.,
Brück Thomas,
Wolmershäuser Gotthelf
Publication year - 1988
Publication title -
chemische berichte
Language(s) - German
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19881210518
Subject(s) - chemistry , thermal decomposition , white phosphorus , decomposition , phosphorus , medicinal chemistry , stereochemistry , crystallography , organic chemistry
Die Thermolyse von weißem Phosphor (P 4 ) und [(η 5 ‐C 5 Me 4 R)‐Fe(CO) 2 ] 2 ( 1 ) sowie [(η 5 ‐C 5 Me 4 R)Ru(CO) 2 Br] ( 2 ) ergibt die gemischten Sandwichkomplexe [(η 5 ‐P 5 )M(η 5 ‐C 5 Me 4 R)] ( 3a,b : M = Fe, R = CH 3 , C 2 H 5 ; 3c,d : M = Ru, R = CH 3 , C 2 H 5 ). 3b und 3d wurden kristallstrukturanalytisch charakterisiert.

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