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Darstellung und Charakterisierung von Hexakis(trifluormethyl)digermachalkogenanen
Author(s) -
Haas Alois,
Kutsch H.Jürgen
Publication year - 1988
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19881210429
Subject(s) - chemistry , trifluoromethyl , medicinal chemistry , stereochemistry , nuclear magnetic resonance spectroscopy , fluorine 19 nmr , organic chemistry , alkyl
Preparation and Characterisation of Hexakis(trifluoromethyl)digermachalcogenanes Reactions of (CF 3 ) 3 GeI ( 2a ) with HgS or Ag 2 Se and of (CF 3 ) 3 GeCl ( 2b ) with ( t ‐BuMe 2 Si) 2 Te ( 3 ) lead to new compounds of the type [(CF 3 ) 3 Ge] 2 E (E = S, Se, Te) ( 1b – d ). 19 F‐, 13 C‐, and 77 Se‐NMR as well as IR‐ and MS data of the compounds are presented and discussed.