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Komplexchemie perhalogenierter Cyclopentadiene und Alkine, I. Metallierung von (C 5 Cl 4 Br)Mn(CO) 3 und Umsetzungen mit Elektrophilen
Author(s) -
Sünkel Karlheinz,
Motz Doris
Publication year - 1988
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19881210428
Subject(s) - chemistry , electrophile , metalation , cyclopentadiene , medicinal chemistry , yield (engineering) , organic chemistry , catalysis , materials science , metallurgy
Coordination Chemistry of Perhalogenated cyclopentadienes and Alkynes, I. — metalation of (C 5 Cl 4 Br)Mn(CO) 3 and Reactions with Electrophiles Lithiation of (C 5 Cl 4 Br)Mn(CO) 3 with n ‐butyllithium gives the isolable, but very air‐sensitive (C 5 Cl 4 Li)Mn(CO) 3 ( 2 ), which reacts with a series of electrophiles to yield (C 5 Cl 4 Br)Mn(CO) 3 ( 3 ), where E = H, Me, SiR 3 , CO 2 R or SR.