Synthese von Bis(η 5 ‐cyclopentadienyl)(1,2,3‐triphenyltriphosphan‐1,3‐diyl)zirconium(IV) und ‐hafnium(IV),  (M = Zr, Hf) und Struktur des Hafnocenderivates | Zendy

Hey Evamarie | Zendy; Bott Simon G. | Zendy; Atwood Jerry L. | Zendy

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Synthese von Bis(η 5 ‐cyclopentadienyl)(1,2,3‐triphenyltriphosphan‐1,3‐diyl)zirconium(IV) und ‐hafnium(IV), (M = Zr, Hf) und Struktur des Hafnocenderivates

Author(s) -

Hey Evamarie,

Bott Simon G.,

Atwood Jerry L.

Publication year - 1988

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19881210327

Subject(s) - hafnium , chemistry , zirconium , metallacycle , cyclopentadienyl complex , crystal structure , metallocene , derivative (finance) , diastereomer , medicinal chemistry , crystallography , x ray crystallography , stereochemistry , inorganic chemistry , organic chemistry , catalysis , polymerization , polymer , optics , physics , diffraction , financial economics , economics

Synthesis of Bis(η 5 ‐cylopentadienyl)(1,2,3‐triphenyltriphosphane‐1,3‐diyl)zirconium(IV) and ‐hafnium(IV) , (M = Zr, Hf), and Structure of the Hafnocene Derivative The reaction of [MCp 2 Cl 2 ] (M = Zr, Hf; Cp = η 5 ‐C 5 H 5 ) with [LiPHPh · 2 THF] and of [ZrCp 2 Me 2 ] with PH 2 Ph leads to ( 1a , M = Zr; 1b , M = Hf). The crystal structure of 1b shows that only one diastereomer is present [( R ) at P(1), ( S ) at P(3)] and that the HfP 3 metallacycle is virtually coplanar.

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