Arene hydrides, 4. Reaction of anthracene hydride (anion of 9,10‐dihydroanthracene) with diaryl ketones. Base‐induced fragmentation of the carbonyl adduct | Zendy

Sommer Andreas | Zendy; Stamm Helmut | Zendy; Woderer Anton | Zendy

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Arene hydrides, 4. Reaction of anthracene hydride (anion of 9,10‐dihydroanthracene) with diaryl ketones. Base‐induced fragmentation of the carbonyl adduct

Author(s) -

Sommer Andreas,

Stamm Helmut,

Woderer Anton

Publication year - 1988

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19881210230

Subject(s) - chemistry , benzophenone , anthracene , hydride , adduct , fluorenone , ketone , medicinal chemistry , fragmentation (computing) , photochemistry , organic chemistry , fluorene , hydrogen , polymer , computer science , operating system

With benzophenone ( 1a ) and fluorenone ( 1b ) anthracene hydride ( AH − ) rapidly forms the anions 3a, b of the corresponding tertiary alcohols 4a, b , the intense colour of the reaction mixture indicating the presence of the ketyls 2a, b . Excess of AH − converts 3a, b into the diarylcarbinols. a mechanism is proposed for this ketone reduction.

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