Reduktive Arylierung von Vinyl‐trifluoromethansulfonaten durch Friedel‐Crafts‐Reaktion | Zendy

García Martínez A. | Zendy; Martínez Alvarez R. | Zendy; García Fraile A. | Zendy; Hanack Michael | Zendy; Subramanian L. R. | Zendy

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Reduktive Arylierung von Vinyl‐trifluoromethansulfonaten durch Friedel‐Crafts‐Reaktion

Author(s) -

García Martínez A.,

Martínez Alvarez R.,

García Fraile A.,

Hanack Michael,

Subramanian L. R.

Publication year - 1987

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19871200724

Subject(s) - chemistry , friedel–crafts reaction , toluene , benzene , polymer chemistry , alkyl , substrate (aquarium) , organic chemistry , medicinal chemistry , catalysis , oceanography , geology

Reductive Arylation of Vinyl Trifluromethanesulfonates by Friedel‐Crafts Reaction The reaction of vinyl triflates 1 with benzene and toluene in the presence of aluminium trichloride gives alkyl‐, alkenyl‐, and 1,1‐diarylalkanes 5, 6, 3, 9 depending on the structure of the substrate used. A mechanism for the reductive arylation is proposed.

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