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Reduktive Arylierung von Vinyl‐trifluoromethansulfonaten durch Friedel‐Crafts‐Reaktion
Author(s) -
García Martínez A.,
Martínez Alvarez R.,
García Fraile A.,
Hanack Michael,
Subramanian L. R.
Publication year - 1987
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19871200724
Subject(s) - chemistry , friedel–crafts reaction , toluene , benzene , polymer chemistry , alkyl , substrate (aquarium) , organic chemistry , medicinal chemistry , catalysis , oceanography , geology
Reductive Arylation of Vinyl Trifluromethanesulfonates by Friedel‐Crafts Reaction The reaction of vinyl triflates 1 with benzene and toluene in the presence of aluminium trichloride gives alkyl‐, alkenyl‐, and 1,1‐diarylalkanes 5, 6, 3, 9 depending on the structure of the substrate used. A mechanism for the reductive arylation is proposed.