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Eine einfache Methode zur Herstellung stannylierter Diaminosulfane
Author(s) -
Hänssgen Dieter,
Plum Robert
Publication year - 1987
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19871200629
Subject(s) - chemistry , sulfur , butyllithium , medicinal chemistry , polymer chemistry , organic chemistry
A Simple Method for the Preparation of Stannylated Diamino‐sulfanes On heating sulfinimidamides t BuS(NRNR 1 (SnMe 3 ) ( 3 ) (obtained in the stepwise reaction of sulfur diimides 1 with tert ‐butyllithium and chlorotrimethylstannane) a reductive elimination of isobutene takes place and the stannylated diaminosulfanes (Me 3 Sn)R 1 NSNHR 2 ( 4 ) are formed in good yields. Some properties of these new compounds are reported.