Premium
Beiträge zur Chemie des Bors, 185 Reaktionen von Metallcarben‐Komplexen mit ( tert ‐Butylimino)‐ (2,2,6,6‐tetramethylpiperidino)boran
Author(s) -
Nöth Heinrich,
Wietelmann Ulrich
Publication year - 1987
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19871200530
Subject(s) - chemistry , medicinal chemistry , acetylene , derivative (finance) , stereochemistry , organic chemistry , economics , financial economics
[2 + 2] Cycloaddition of the aminoiminoborane 1 with Cp 2 ‐TiCH 2 yields a blue 1‐aza‐2‐bora‐4‐titanacyclobutane derivative 2 . In contrast, Fischer carbenes (CO) 5 M = C(OMe)Me (MCr, W) react in a complex way to produce 1 · M(CO) 5 ( 4 ), tmpB(NHCMe 3 )OMe ( 5 ), and the borylated acetylene derivative 6 .
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom