Desaminierungsreaktionen, 47 Zerfall von 1‐(3‐Hydroxypropyl)cyclopropandiazonium‐Ionen | Zendy

Kirmse Wolfgang | Zendy; Rode Klaus | Zendy

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Desaminierungsreaktionen, 47 Zerfall von 1‐(3‐Hydroxypropyl)cyclopropandiazonium‐Ionen

Author(s) -

Kirmse Wolfgang,

Rode Klaus

Publication year - 1987

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19871200525

Subject(s) - chemistry , intramolecular force , intermolecular force , cleavage (geology) , nucleophilic substitution , product distribution , medicinal chemistry , diazonium compounds , ion , nucleophile , bond cleavage , intramolecular reaction , stereochemistry , molecule , organic chemistry , catalysis , geotechnical engineering , fracture (geology) , engineering

The diazonium ions 13 have been generated by alkaline cleavage of the analogous nitrosocarbamate 12 . The product distribution indicates little participation of the hydroxy group (0.4% 9 ) while the allyl cation 14 arising from 13 undergoes intramolecular (4.3% 17 ) as well as intermolecular (75% 16 ) nucleophilic substitution.

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