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Desaminierungsreaktionen, 47 Zerfall von 1‐(3‐Hydroxypropyl)cyclopropandiazonium‐Ionen
Author(s) -
Kirmse Wolfgang,
Rode Klaus
Publication year - 1987
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19871200525
Subject(s) - chemistry , intramolecular force , intermolecular force , cleavage (geology) , nucleophilic substitution , product distribution , medicinal chemistry , diazonium compounds , ion , nucleophile , bond cleavage , intramolecular reaction , stereochemistry , molecule , organic chemistry , catalysis , geotechnical engineering , fracture (geology) , engineering
The diazonium ions 13 have been generated by alkaline cleavage of the analogous nitrosocarbamate 12 . The product distribution indicates little participation of the hydroxy group (0.4% 9 ) while the allyl cation 14 arising from 13 undergoes intramolecular (4.3% 17 ) as well as intermolecular (75% 16 ) nucleophilic substitution.