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Aufbau eines achtgliedrigen Bor—Stickstoff—Phosphor‐Heterocyclus aus PhNHPPh 2 NPh und H 3 BSMe 2
Author(s) -
SüßFink Georg
Publication year - 1986
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19861190732
Subject(s) - chemistry , phosphorane , borane , mass spectrum , molecule , stereochemistry , boron , crystallography , nitrogen , medicinal chemistry , catalysis , organic chemistry , ion
Assembly of an Eight‐Membered Boron—Nitrogen—Phosphorus Heterocycle from PhNHPPh 2 NPh and H 3 BSMe 3 The eight‐membered molecule ( 1 ) was synthesized by the reaction of the amino‐imino‐phosphorane PhNHPPh 2 NPh with dimethylsulfane—borane. As a side‐product PhNHPPh 2 BH 3 ( 2 ) was isolated. Both compounds were characterised by their IR, 1 H‐, 31 P‐, 11 B‐NMR, and mass spectra.