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Synthese und Struktur des kationischen Tetrahydrofuran‐Eisenkomplexes [C 5 Me 5 (CO)(Me 3 P)(THF)Fe] +
Author(s) -
Grötsch Georg,
Boese Roland,
Malisch Wolfgang
Publication year - 1986
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19861190727
Subject(s) - chemistry , tetrahydrofuran , cationic polymerization , ligand (biochemistry) , medicinal chemistry , stereochemistry , polymer chemistry , organic chemistry , receptor , solvent , biochemistry
Synthesis and Structure of the Cationic Tetrahydrofuran Iron Complex [C 5 Me 5 (CO)(Me 3 P)(THF)F] + The reaction of C 5 Me 5 (CO)(Me 3 P)FeMe ( 1 ) with [Ph 3 C]PF 6 in THF leads to the complex salt [C 5 Me 5 (CO)(Me 3 P)(THF)Fe]PF 6 ( 2 ), which exchanges the THF ligand against Me 3 P under photochemical conditions to give [C 5 Me 5 (CO)(Me 3 P) 2 Fe]PF 6 ( 3 ).